%0 Conference Proceedings %T Electroforming Process in Metal-Oxide-Polymer Resistive Switching Memories %+ Center of Electronics Optoelectronics and Telecommunications [Faro] (CEOT) %+ Philips Research Laboratories [Eindhoven] %+ Eindhoven University of Technology [Eindhoven] (TU/e) %A Chen, Qian %A Gomes, Henrique, L. %A Kiazadeh, Asal %A Rocha, Paulo, F. %A Leeuw, Dago, De %A Meskers, Stefan, J. %Z Part 18: Electronic Materials %< avec comité de lecture %( IFIP Advances in Information and Communication Technology %B 3rd Doctoral Conference on Computing, Electrical and Industrial Systems (DoCEIS) %C Costa de Caparica, Portugal %Y Luis M. Camarinha-Matos %Y Ehsan Shahamatnia %Y Gonçalo Nunes %I Springer %3 Technological Innovation for Value Creation %V AICT-372 %P 527-534 %8 2012-02-27 %D 2012 %R 10.1007/978-3-642-28255-3_58 %K Resistive Random Access Memory (RRAM) %K electroforming softbreakdown %K non-volatile memory %Z Computer Science [cs]Conference papers %X Electroforming of an Al/Al2O3/polymer/Al resistive switching diode is reported. Electroforming is a dielectric soft-breakdown mechanism leading to hysteretic current–voltage characteristics and non–volatile memory behavior. Electron trapping occurs at early stages of electroforming. Trapping is physically located at the oxide/polymer interface. The detrapping kinetics is faster under reverse bias and for thicker oxides layers. Thermally detrapping experiments give a trap depth of 0.65 eV and a density of 5x1017 /cm2. It is proposed that the trapped electrons induce a dipole layer across the oxide. The associated electric field triggers breakdown and ultimately dictate the overall memory characteristics. %G English %Z TC 5 %Z WG 5.5 %2 https://inria.hal.science/hal-01365772/document %2 https://inria.hal.science/hal-01365772/file/978-3-642-28255-3_58_Chapter.pdf %L hal-01365772 %U https://inria.hal.science/hal-01365772 %~ IFIP %~ IFIP-AICT %~ IFIP-TC %~ IFIP-TC5 %~ IFIP-WG %~ IFIP-WG5-5 %~ IFIP-DOCEIS %~ IFIP-AICT-372